Anorthite is the calcium-rich endmember of the plagioclase solid solution series, the other endmember being albite, NaAlSi3O8. Anorthite also refers to plagioclase compositions with more than 90 molecular percent of the anorthite endmember.
Anorthite is a rare compositional variety of plagioclase. It occurs in mafic igneous rock. It also occurs in granulite facies metamorphic rocks, in metamorphosed carbonate rocks and corundum deposits. Its type localities are Monte Somma and Valle di Fassa, Italy. It was first described in 1823. It is more rare in surficial rocks than it normally would be due to its high weathering potential in the Goldich dissolution series.
It also makes up much of the lunar highlands; the Genesis Rock is made of anorthosite, which is composed largely of anorthite. Anorthite was discovered in samples from comet Wild 2, and the mineral is an important constituent of Ca-Al-rich inclusions in rare varieties of chondritic meteorites.